Molecular Beam Studies of Bimolecular Reactions: F + H2 and Li + HF
نویسندگان
چکیده
منابع مشابه
Polarization of molecular angular momentum in the chemical reactions Li + HF and F + HD.
The quantum mechanical approach to vector correlation of angular momentum orientation and alignment in chemical reactions [G. Balint-Kurti and O. S. Vasyutinskii, J. Phys. Chem. A 113, 14281 (2009)] is applied to the molecular reagents and products of the Li + HF [L. Gonzalez-Sanchez, O. S. Vasyutinskii, A. Zanchet, C. Sanz-Sanz, and O. Roncero, Phys. Chem. Chem. Phys. 13, 13656 (2011)] and F +...
متن کاملpostnatal studies of bats (pipistrellus kuhlii and miniopterus schreibersii) & histomorphology and histochemistry studies of organs and diseases of (neurergus microspilotus and n. kaiseri)
1. to determine whether difference in birth body mass influenced growth performance in pipistrellus kuhlii we studied a total of 12 captive-born neonates. bats were assigned to two body mass groups: light birth body mass (lbw: 0.89 ± 0.05, n=8) and heavy birth body mass (hbw: 1.35 ± 0.08, n=4). heavier body mass at birth was associated with rapid postnatal growth (body mass and forearm length) ...
Mode selective dynamics and kinetics of the H2 + F2 → H + HF + F reaction.
The reaction between vibrationally excited H2 and F2 had previously been suggested to be a critical chain-branching step in the combustion of mixtures containing H2 and F2. In the present study, the vibrational state specific dynamics and kinetics for the reaction H2 + F2 → H + HF + F were investigated by quasiclassical trajectory (QCT) and quantum mechanical (QM) reactive scattering calculatio...
متن کاملVibrationally resolved transition state spectroscopy of the F + H2 and F + CH4 reactions.
The transition state regions of the F + para-H2, F + normal-H2, F + CH4 and F + CD4 reactions have been studied by slow electron velocity-map imaging (SEVI) spectroscopy of the anionic precursor clusters para-FH2-, normal-FH2-, FCH4 and FCD4. The F + H2 results improve on previously published photoelectron spectra, resolving a narrow peak that appears in the same position in the para-FH2 and no...
متن کاملEquilibration in Reversible Bimolecular Reactions
Fast reversible pseudo-unimolecular reactions do not approach equilibrium in the simple exponential fashion predicted by chemical rate equations. Many-body effects in bimolecular reactions have been revealed in an extensive series of Brownian simulations, showing up to three distinct phases in the approach to equilibrium. Recent theoretical developments are compared with the simulation as well ...
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ژورنال
عنوان ژورنال: Berichte der Bunsengesellschaft für physikalische Chemie
سال: 1982
ISSN: 0005-9021
DOI: 10.1002/bbpc.19820860510